Colored Fire is a common pyrotechnic effect used in stage productions, fireworks and by fire performers the world over. Generally, the color of a flame A flame is the visible (light-emitting) gaseous part of a fire. It is caused by a highly exothermic reaction (for example, combustion, a self-sustaining oxidation reaction) taking place in a thin zone. If a fire is hot enough to ionize the gaseous components, it can become a plasma may be red, orange, yellow, or white, and is dominated by blackbody radiation Thermal radiation is electromagnetic radiation emitted from the surface of an object which is due to the object's temperature. An example of thermal radiation is the infrared radiation emitted by a common household radiator or electric heater. A person near a raging bonfire will feel the radiated heat of the fire, even if the surrounding air is from soot Soot is a general term that refers to impure carbon particles resulting from the incomplete combustion of a hydrocarbon. It is more properly restricted to the product of the gas-phase combustion process but is commonly extended to include the residual pyrolyzed fuel particles such as cenospheres, charred wood, petroleum coke, etc. that may become and steam Steam is either mist , or the gas phase of water (water vapor). When additional chemicals are added to the fuel burning, their atomic emission The two states must be bound states in which the electron is bound to the atom, so the transition is sometimes referred to as a "bound–bound" transition, as opposed to a transition in which the electron is ejected out of the atom completely into a continuum state, leaving an ionized atom, and generating continuum radiation spectra can affect the frequencies of visible light radiation emitted - in other words, the flame will appear a different color dependent upon the chemical additives. Flame coloring is also a good way to demonstrate how chemicals change when subjected to heat and how they also change the matter around them.
Pyrotechnicians will generally use metal salts to color their flames. Specific combinations of fuels and co-solvents are required in order to dissolve the necessary chemicals. Color enhancers (usually chlorine donors) are frequently added too, the most common of which is polyvinyl chloride Polyvinyl chloride, (IUPAC Poly) commonly abbreviated PVC, is a thermoplastic polymer. It is a vinyl polymer constructed of repeating vinyl groups (ethenyls) having one of their hydrogens replaced with a chloride group.
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Flame Colorants
Main article: Pyrotechnic colorant A pyrotechnic colorant is a chemical compound which causes a flame to burn with a particular color. These are used to create the colors in pyrotechnic compositions like fireworks and colored fires. Some common examples are:Emitted colors depend on the electronic configuration of the elements involved. Heat energy from the flame excites electrons to a higher quantum level, and the atoms emit characteristic colors (photons with energies corresponding to the visible spectrum) as they return to lower energy levels.
Campfire Colorants
Main article: Pyrotechnic composition A pyrotechnic composition is a substance or mixture of substances designed to produce an effect by heat, light, sound, gas or smoke or a combination of these, as a result of non-detonative self-sustaining exothermic chemical reactions. Pyrotechnic substances do not rely on oxygen from external sources to sustain the reactionFlame colorants are becoming popular while camping. Scouts and other outdoor enthusiasts have placed sections of copper Copper is a chemical element with the symbol Cu (Latin: cuprum) and atomic number 29. It is a ductile metal with very high thermal and electrical conductivity. Pure copper is rather soft and malleable, and a freshly exposed surface has a pinkish or peachy color. It is used as a thermal conductor, an electrical conductor, a building material, and a pipe with holes drilled throughout and stuffed with garden hose onto campfires to create a variety of flame colors. An easier and more accepted method of coloring campfires has been fueled by commercial products. These packages of flame colorants are tossed onto a campfire A campfire is a fire lit at a campsite, giving light, warmth and allowing cooking. In established campgrounds they are usually in a fire ring for safety. Campfires are a popular feature of camping, particularly among organized campers such as Scouts or Guides. In some regions it is called a bonfire, especially when it is of a very large size or into a fireplace to produce effects.
Although these chemicals are very effective at imparting their color into an already existing flame, these substances are not flammable alone. To produce a powder or solid that, when lit, produces a colored flame, the necessary steps are more complex. To get a powder to burn satisfactorily, both a fuel and oxidizer will probably be needed. Common oxidizers include:
- Ammonium perchlorate It is produced by reaction between ammonia and perchloric acid, and is the driver behind the industrial production of perchloric acid. It also can be prepared by treatment of ammonium salts with sodium perchlorate. This process exploits the fact that the solubility of NH4ClO4 is about 10% of that for sodium perchlorate
- Ammonium nitrate The chemical compound ammonium nitrate, the nitrate of ammonia with the chemical formula N
- Barium nitrate Baratol is an explosive composed of barium nitrate, TNT and binder; the high density of barium nitrate results in baratol being quite dense as well. Barium nitrate mixed with aluminium powder, a formula for flash powder, is highly explosive. It is mixed with Thermite to form Thermate-TH3, used in military thermite grenades. It is also used in the
- Barium chlorate Barium chlorate is a white crystalline solid. It is an irritant, and if consumed can cause nausea, vomiting, and diarrhoea. It is used in pyrotechnics to produce a green colour
- Guanine nitrate
- Potassium nitrate Potassium nitrate is a chemical compound with the chemical formula K (saltpeter)
- Potassium chlorate Potassium chlorate is a compound containing potassium, chlorine and oxygen, with the molecular formula KClO3. In pure form, it is a white crystalline substance. It is the most common chlorate in industrial use, and is usually present in well-stocked laboratories. It is used
- Potassium perchlorate KClO4 is prepared industrially by treating an aqueous solution of sodium perchlorate with KCl. This ion exchange process exploits the low solubility of KClO4, which is about 100 times less than the solubility of NaClO4
- Strontium nitrate Strontium nitrate is typically generated by the reaction of nitric acid on strontium carbonate
- Sodium nitrate Sodium nitrate is the chemical compound with the formula NaNO3. This salt, also known as "Chile saltpeter" or "Peru saltpeter" , is a white solid which is very soluble in water. The mineral form is also known as nitratine or soda niter
Really there are a few simple rules for deciding which oxidizer to use when:
1. Metal color:
See also
Notes
External links
Categories: Pyrotechnics
Thu, 22 Jul 2010 18:12:44 GMT+00:00
Port Orchard Independent ... wearing a gray- colored hooded sweatshirt with jeans and was witnessed leaving the scene in a maroon- colored vehicle. South Kitsap Fire and Rescue (SKFR) ...
